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THE HALOGENATION OF ALKANES AND CYCLOALKANES

This page describes the reactions between alkanes and cycloalkanes with the halogens fluorine, chlorine, bromine and iodine - mainly concentrating on chlorine and bromine. Alkanes The reaction between alkanes and fluorine This reaction is explosive even in the cold and dark, and you tend to get carbon and hydrogen fluoride produced. It is of no particular interest. For example: The reaction between alkanes and iodine Iodine doesn't react with the alkanes to any extent - at least, under normal lab conditions. The reactions between alkanes and chlorine or bromine There is no reaction in the dark. In the presence of a flame, the reactions are rather like the fluorine one - producing a mixture of carbon and the hydrogen halide. The violence of the reaction drops considerably as you go from fluorine to chlorine to bromine. The int...